By Daniel V. Schroeder

ISBN-10: 0201380277

ISBN-13: 9780201380279

This article appears to be like at thermodynamics and statistical mechanics. half I introduces techniques of thermodynamics and statistical mechanics from a unified view. components II and III discover extra functions of classical thermodynamics and statistical mechanics. all through, the emphasis is on real-world functions.

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The same would be true if one molecule had radius 21' and the other were a point. When a sphere of radius 21' moves in a straight line of length £, it sweeps out a cylinder whose volume is 411T 2 e. 5 x 10- 10 m. Treating air as an ideal gas, angstroms; let's say r the volume per particle is V/N kT/ P = 4 X 10- 26 m 3 at room temperature and atmospheric pressure. 62 predicts a mean free path of 150 nm, about 40 times greater than the average separation between air molecules. We can also estimate the average time between collisions: f!

Would you classify the flow of energy from the battery to the resistor as "heat" or "work"? What about the flow of energy from the resistor to the water? 27. Give an example of a process in which no heat is added to a system, but its temperature increases. Then give an example of the opposite: a process in which heat is added to a system but its temperature does not change. *Among the many others who helped establish the first law were Benjamin Thompson (Count Rumford), Robert Mayer, William Thomson, and Hermann von Helmholtz.

Although perfectly quasistatic compression is an idealization, it is usually a good approximation in practice. To compress the gas non-quasistatically you would have to slam the piston very hard, so it moves faster than the gas can "respond" (the speed must be at least comparable to the speed of sound in the gas). For quasistatic compression, then, the force exerted on the gas equals the pres­ sure of the gas times the area of the piston. * Thus, W=PA~x (for quasistatic compression). 27) But the product A ~x is just minus the change in the volume of the gas (minus because the volume decreases when the piston moves in), so W = -P~V (quasistatic) .

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An Introduction to Thermal Physics by Daniel V. Schroeder

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